PastryJoe, while writing about the history of Irish Sourdough Bread, traced the history of chemical leavening agents, as opposed to the more ancient technique of only yeast as leavening agent. — Potash: Native Americans used wood ashes to “lighten” their grain cakes. Pearl ash: made by baking potash in a kiln to remove impurities. Saleratus: made by adding carbonic acid to pearlash. Another favorite source for the history of Pearl Ash to Baking Soda is from the Taste of Carolina. Photo, left, shows a sourdough yeast at room temperature which is fed twice daily with flour and water. This yeast leavening is different, an older form of leavening, than chemical leavening agents we’re discussing.
Then you can pick up the timeline of chemical leavening agents at History of Baking Powder by Whats Cooking America. Additionally, Rumford Baking Powder was first available in stores in 1859.
Baking powder has been made with different ingredients at different times: now baking powder is made with sodium bicarbonate and monocalcium phosphate, or, sodium bicarbonate and sodium aluminum sulfate, or just calcium acid phosphate. Corn starch is often an ingredient added to postpone activity if the baking powder is in contact with moisture, allowing the baking powder to be active later when it is heated in the oven.
Note from wikipedia: “…In times past, when chemically manufactured baking soda was not available, ash water was used instead, especially in confectionery. Wood ash is also weakly alkaline. To prepare ash water, one used a fistful of ash from the fireplace in a big pot of water. Ash from solid woods, such as the olive tree, is preferred, whereas resinous woods, like pine, cannot be used. The ash water is given a boil, then left overnight to settle. The water is then filtered through a cloth and is ready to use. Many traditional recipes call for ash water instead of baking soda, because of some unique qualities: for example, ash water dripped on hot vegetable oils congeals into a gel-like mixture…”
Asides:
- The word potassium is derived from the word potash.
- When cooks switched from potash, or pearl ash, to saleratus, they could use fewer eggs.
Link to Baking Powder & Corn Starch Booklets.